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How a protein repurposes vitamin B12 as a light sensor

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It is essential for many organisms to be able to respond to light. Biological systems use photoreceptor proteins to detect light through molecules known as chromophores. The bacterial photoreceptor CarH uses a vitamin B 12 derivative called adenosylcobalamin (AdoCbl) as a chromophore, co-opting it from its normal function as a cofactor for enzymatic reactions1,2. Writing in Nature, a collaboration of several international teams of scientists (Rios-Santacruz et al.3) report that they have used cutting-edge structural-biology methods to capture snapshots of CarH in action, thereby revealing what happens to AdoCbl as soon as 10 nanoseconds after exposure to light. The findings answer a long-standing question about how CarH controls the light-induced breakdown of AdoCbl.

doi: https://doi.org/10.1038/d41586-026-00169-9

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Competing Interests The authors declare no competing interests.

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