Scientists detect weaker chemical bonds in superheavy element seaborgium
Researchers at GSI Darmstadt synthesized the superheavy isotope 259Sg and formed a volatile hexacarbonyl compound, Sg(CO)6, comparing its behavior to tungsten carbonyl compounds made from short-lived isotopes. By tracking how these complexes moved through a temperature-gradient chromatography column, the team measured bonding properties of seaborgium directly for only the second time ever.
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The findings offer rare experimental evidence that relativistic effects—distortions in electron behavior caused by very heavy atomic nuclei—can weaken chemical bonds in superheavy elements, supporting theoretical predictions that are otherwise hard to test. Because these elements exist for only fractions of a second and must be made atom-by-atom in accelerators, such measurements help scientists understand whether heavy elements follow or break the periodic trends expected from their lighter counterparts.
- Seaborgium-259 and tungsten isotopes were produced via nuclear fusion reactions at GSI Darmstadt's UNILAC accelerator.
- Volatile hexacarbonyl complexes were studied using gas chromatography to infer chemical bonding strength.
- Results point to relativistic bond weakening in seaborgium compared to its lighter homologue tungsten.
Source: nature.com — Yakushev, 2026-10-07
Published there as: “Observation of relativistic bond weakening in seaborgium hexacarbonyl”
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